Spacer-Controlled Supramolecular Assemblies of Cu(II) with Bis(2-Hydroxyphenylimine) Ligands. from Monoligand Complexes to Double-Stranded Helicates and Metallomacrocycles

Spacer-Controlled Supramolecular Assemblies of Cu(II) with Bis(2-Hydroxyphenylimine) Ligands. from Monoligand Complexes to Double-Stranded Helicates and Metallomacrocycles

Reaction of Cu(NO3)2·3H2O or Cu(CH3COO)2·H2O with the bis(2-hydroxyphenylimine) ligands H2L1-H2L4 gave four Cu(II) complexes of composition [Cu2(L1)(NO3)2(H2O)]·MeOH, [Cu2(L2)2], [Cu2(L3)2] and [Cu2(L4)2]·2MeOH. Depending on the spacer unit, the structures are characterized by a dinuclear arrangemen...

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Bibliographic Details
Main Authors: Norman Kelly, Franziska Taube, Kerstin Gloe, Thomas Doert, Wilhelm Seichter, Axel Heine, Jan J. Weigand, Karsten Gloe
Format: Article
Language:English
Published: MDPI AG 2016-09-01
Series:Crystals
Subjects:
self-assembly
copper(II)
Schiff bases
coordination patterns
helicates
metallomacrocycles
Online Access:http://www.mdpi.com/2073-4352/6/9/120

Internet

http://www.mdpi.com/2073-4352/6/9/120

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