Crystal structure of cyclo-bis(μ4-2,2-diallylmalonato-κ6O1,O3:O3:O1′,O3′:O1′)tetrakis(triphenylphosphane-κP)tetrasilver(I)

Crystal structure of cyclo-bis(μ4-2,2-diallylmalonato-κ6O1,O3:O3:O1′,O3′:O1′)tetrakis(triphenylphosphane-κP)tetrasilver(I)

In the tetranuclear molecule of the title compound, [Ag4(C9H10O4)2(C18H15P)4], the AgI ion is coordinated by one P and three O atoms in a considerably distorted tetrahedral environment. The two 2,2-diallylmalonate anions bridge four AgI ions in a μ4-(κ6O1,O3:O3:O1′,O3′:O1′) mode, setting up an Ag4O8...

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Bibliographic Details
Main Authors: Peter Frenzel, Alexander Jakob, Dieter Schaarschmidt, Tobias Rüffer, Heinrich Lang
Format: Article
Language:English
Published: International Union of Crystallography 2014-10-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
silver(I)
malonate ligand
phosphane ligand
Ag4O8P4 core
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814019394

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http://scripts.iucr.org/cgi-bin/paper?S1600536814019394

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