Ethanol- and Methanol-Coordinated and Solvent-Free Dodecahydro <i>closo</i>-Dodecaborates of 3<i>d</i> Transition Metals and of Magnesium

Ethanol- and Methanol-Coordinated and Solvent-Free Dodecahydro <i>closo</i>-Dodecaborates of 3<i>d</i> Transition Metals and of Magnesium

Magnesium and 3<i>d</i> transition metals <i>closo</i>-borates were prepared by mechanosynthesis (ball milling) of the mixtures Na<sub>2</sub>B<sub>12</sub>H<sub>12</sub> + MCl<sub>2</sub> (M = Mn, Fe, Co, Ni, Mg), followed by a...

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Bibliographic Details
Main Authors: Emilie Didelot, Zbigniew Łodziana, Fabrizio Murgia, Radovan Černý
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Crystals
Subjects:
<i>Closo</i>-borate
transition metal
ethanol complex
methanol complex
X-ray powder diffraction
Online Access:https://www.mdpi.com/2073-4352/9/7/372

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https://www.mdpi.com/2073-4352/9/7/372

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