Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit

Abstract This work reports the properties of GaN films grown onto c-Si (100) at relatively low substrate temperature (400°C) by reactive magnetron sputtering. The study depicts the effect of working pressure and RF power on the GaN film structural, vibrational and optical properties characterized by...

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Main Authors: R. S. de Oliveira, H. A. Folli, C. Stegemann, I. M. Horta, B. S. Damasceno, W. Miyakawa, A. L. J. Pereira, M. Massi, A. S. da Silva Sobrinho, D. M. G. Leite
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2022-01-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392022000100240&lng=en&tlng=en
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author R. S. de Oliveira
H. A. Folli
C. Stegemann
I. M. Horta
B. S. Damasceno
W. Miyakawa
A. L. J. Pereira
M. Massi
A. S. da Silva Sobrinho
D. M. G. Leite
author_facet R. S. de Oliveira
H. A. Folli
C. Stegemann
I. M. Horta
B. S. Damasceno
W. Miyakawa
A. L. J. Pereira
M. Massi
A. S. da Silva Sobrinho
D. M. G. Leite
author_sort R. S. de Oliveira
collection DOAJ
description Abstract This work reports the properties of GaN films grown onto c-Si (100) at relatively low substrate temperature (400°C) by reactive magnetron sputtering. The study depicts the effect of working pressure and RF power on the GaN film structural, vibrational and optical properties characterized by X-ray diffraction, atomic force and scanning electron microscopies, Raman spectroscopy and spectroscopic ellipsometry. Unusual low pressure deposition condition (0.40 Pa) was achieved by using a separated argon inlet directed to the Ga target surface, resulting in improved crystalline quality of the films. In this condition, the preferential crystalline orientation, the surface morphology and the optical gap of the GaN films show a strong dependence on the RF power applied to the Ga target, where low RF power (30-60 W) was responsible for increasing the c-axis orientation and the optical gap, while higher RF power (75-90 W) decreased the overall crystal quality and increased the surface roughness.
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publishDate 2022-01-01
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spelling doaj.art-2117ac92ff414944a2e3510f8165c2bb2022-12-21T19:48:27ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392022-01-012510.1590/1980-5373-mr-2021-0432Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure LimitR. S. de OliveiraH. A. FolliC. StegemannI. M. HortaB. S. DamascenoW. MiyakawaA. L. J. PereiraM. Massihttps://orcid.org/0000-0002-7117-8039A. S. da Silva Sobrinhohttps://orcid.org/0000-0001-7227-9176D. M. G. Leitehttps://orcid.org/0000-0002-1792-6171Abstract This work reports the properties of GaN films grown onto c-Si (100) at relatively low substrate temperature (400°C) by reactive magnetron sputtering. The study depicts the effect of working pressure and RF power on the GaN film structural, vibrational and optical properties characterized by X-ray diffraction, atomic force and scanning electron microscopies, Raman spectroscopy and spectroscopic ellipsometry. Unusual low pressure deposition condition (0.40 Pa) was achieved by using a separated argon inlet directed to the Ga target surface, resulting in improved crystalline quality of the films. In this condition, the preferential crystalline orientation, the surface morphology and the optical gap of the GaN films show a strong dependence on the RF power applied to the Ga target, where low RF power (30-60 W) was responsible for increasing the c-axis orientation and the optical gap, while higher RF power (75-90 W) decreased the overall crystal quality and increased the surface roughness.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392022000100240&lng=en&tlng=enGaNreactive sputteringthin film
spellingShingle R. S. de Oliveira
H. A. Folli
C. Stegemann
I. M. Horta
B. S. Damasceno
W. Miyakawa
A. L. J. Pereira
M. Massi
A. S. da Silva Sobrinho
D. M. G. Leite
Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
Materials Research
GaN
reactive sputtering
thin film
title Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
title_full Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
title_fullStr Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
title_full_unstemmed Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
title_short Structural, Morphological, Vibrational and Optical Properties of GaN Films Grown by Reactive Sputtering: The Effect of RF Power at Low Working Pressure Limit
title_sort structural morphological vibrational and optical properties of gan films grown by reactive sputtering the effect of rf power at low working pressure limit
topic GaN
reactive sputtering
thin film
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392022000100240&lng=en&tlng=en
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