First Example of Cage P<sub>4</sub>N<sub>4</sub>-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu<sub>2</sub>I Fragments

First Example of Cage P<sub>4</sub>N<sub>4</sub>-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu<sub>2</sub>I Fragments

In this study, 28-membered macrocyclic 1,5(1,5)-di(1,5-diaza-3,7-diphosphacyclooctana)-2,4,6,8(1,4)-tetrabenzenacyclooctaphane were synthesized by condensation of pyridinephosphine, paraformaldehyde, and primary diamines (bis(4-aminophenyl)methane or -sulfide. The first representatives of binuclear...

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Bibliographic Details
Main Authors: Anna S. Balueva, Yulia A. Nikolaeva, Elvira I. Musina, Igor A. Litvinov, Andrey A. Karasik
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
cyclophanes
cyclic aminomethylphosphines
copper complexes
intracavity
crystal structure
Online Access:https://www.mdpi.com/1420-3049/28/2/680

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https://www.mdpi.com/1420-3049/28/2/680

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