Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate
In the title complex, [Cu(C2H8N2)2(H2O)2](C13H9O2)2·2.66H2O, the CuII centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810016223 |
| _version_ | 1831660909953548288 |
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| author | José A. Fernandes Ana I. Ramos Patrícia Silva Susana S. Braga Paulo Ribeiro-Claro João Rocha Filipe A. Almeida Paz |
| author_facet | José A. Fernandes Ana I. Ramos Patrícia Silva Susana S. Braga Paulo Ribeiro-Claro João Rocha Filipe A. Almeida Paz |
| author_sort | José A. Fernandes |
| collection | DOAJ |
| description | In the title complex, [Cu(C2H8N2)2(H2O)2](C13H9O2)2·2.66H2O, the CuII centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the water molecules are disordered over two distinct crystallographic positions with occupancies of 1/3 and 2/3. In the crystal, the cations and anions are disposed in alternating layers. One of the water molecules of crystallization is disordered and the other has a fractional occupation. In the 2/3 occupancy component, water molecules are organized into a chain composed of hexameric units interconnected by carboxylate bridges. |
| first_indexed | 2024-12-19T18:23:52Z |
| format | Article |
| id | doaj.art-21b3d15367a94ad8b5ed9772ab01c75f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:23:52Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-21b3d15367a94ad8b5ed9772ab01c75f2022-12-21T20:10:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m626m62710.1107/S1600536810016223Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrateJosé A. FernandesAna I. RamosPatrícia SilvaSusana S. BragaPaulo Ribeiro-ClaroJoão RochaFilipe A. Almeida PazIn the title complex, [Cu(C2H8N2)2(H2O)2](C13H9O2)2·2.66H2O, the CuII centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the water molecules are disordered over two distinct crystallographic positions with occupancies of 1/3 and 2/3. In the crystal, the cations and anions are disposed in alternating layers. One of the water molecules of crystallization is disordered and the other has a fractional occupation. In the 2/3 occupancy component, water molecules are organized into a chain composed of hexameric units interconnected by carboxylate bridges.http://scripts.iucr.org/cgi-bin/paper?S1600536810016223 |
| spellingShingle | José A. Fernandes Ana I. Ramos Patrícia Silva Susana S. Braga Paulo Ribeiro-Claro João Rocha Filipe A. Almeida Paz Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate Acta Crystallographica Section E |
| title | Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
| title_full | Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
| title_fullStr | Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
| title_full_unstemmed | Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
| title_short | Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
| title_sort | diaquabis ethylenediamine amp 954 2n n amp 8242 copper ii bis 4 phenylbenzoate 2 66 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810016223 |
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