Gold coordination during homogeneous alkyne and allene cyclisation catalysis: Coordination to substrates, to ancillary ligands and in intermediates
The ever-increasing role of homogeneous gold catalysis in organic synthesis and the consequent need to be able to rationally control the rate and outcome of such reactions has emphasised the importance of each successive metal–carbon coordination step. Concentrating on alkyne and allene cyclisation...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Academy of Science of South Africa
2011-03-01
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Series: | South African Journal of Science |
Subjects: | |
Online Access: | http://archive.sajs.co.za/index.php/SAJS/article/view/459 |