Green synthesis of α-deuterated boronates using DMTT reagent
An efficient method for the synthesis of deuterated homologation of boronate esters was developed. This discovery uses robust deuterated agent 5-(methyl-d3)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethane sulfonate (DMTT) as d2-methylene source. Mechanistically, base promoted deprotonation of DMTT to...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
KeAi Communications Co. Ltd.
2021-08-01
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Series: | Green Synthesis and Catalysis |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S266655492100051X |