Green synthesis of α-deuterated boronates using DMTT reagent

An efficient method for the synthesis of deuterated homologation of boronate esters was developed. This discovery uses robust deuterated agent 5-(methyl-d3)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethane sulfonate (DMTT) as d2-methylene source. Mechanistically, base promoted deprotonation of DMTT to...

Full description

Bibliographic Details
Main Authors: Zedong Zhang, Jian Wen, Minyan Wang, Chao-Guo Yan, Zhuangzhi Shi
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-08-01
Series:Green Synthesis and Catalysis
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S266655492100051X