Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies

Patent Blue (PB) dye removal from an aqueous medium was investigated using pineapple fruit peel biochar (PFPB). The presence of functional groups and surface characteristics of PFPB was studied using Fourier transform infrared spectra (FTIR) and scanning electron microscopy (SEM). A study was conduc...

Full description

Bibliographic Details
Main Authors: Riti Thapar Kapoor, Mohd Rafatullah, Ahmed Muteb Aljuwayid, Mohamed A. Habila, Saikh Mohammad Wabaidur, Mahboob Alam
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Separations
Subjects:
Online Access:https://www.mdpi.com/2297-8739/9/12/426
_version_ 1797455220071989248
author Riti Thapar Kapoor
Mohd Rafatullah
Ahmed Muteb Aljuwayid
Mohamed A. Habila
Saikh Mohammad Wabaidur
Mahboob Alam
author_facet Riti Thapar Kapoor
Mohd Rafatullah
Ahmed Muteb Aljuwayid
Mohamed A. Habila
Saikh Mohammad Wabaidur
Mahboob Alam
author_sort Riti Thapar Kapoor
collection DOAJ
description Patent Blue (PB) dye removal from an aqueous medium was investigated using pineapple fruit peel biochar (PFPB). The presence of functional groups and surface characteristics of PFPB was studied using Fourier transform infrared spectra (FTIR) and scanning electron microscopy (SEM). A study was conducted to assess the pH effect, contact time, concentration of dye, biochar dose, speed of agitation, and temperature on removal of PB (Patent Blue) dye from an aqueous medium by PFPB. The highest 95% elimination of PB dye was reported at pH 2 by PFPB with 600 mg/L concentration of PB dye. Equilibrium studies divulged the favorable adsorption that followed the Langmuir isotherm with a monolayer uptake potential of 10.29 mg/g. Findings of kinetics disclosed that adsorption results were properly explained by the pseudo second-order model. The adsorption phenomenon was exothermic and spontaneous, as observed by thermodynamic variables. PFPB reflected a 37% uptake capacity of PB dye for up to five consecutive cycles in the adsorption and desorption study. A phytotoxicity study exhibited that PFPB-treated PB dye solution enhanced the growth of seedlings and biochemical constituents of lentils. The findings of the present study indicate the immense potential of pineapple fruit peel biochar for anionic dye removal from wastewater systems. Thus, pineapple fruit peel biochar can be utilized as a promising green sorbent for the elimination of Patent Blue dye in industrial effluents, as it is widely available and converts wastewater into reusable assets.
first_indexed 2024-03-09T15:51:16Z
format Article
id doaj.art-232cfb35574c428d9ee59a446d99629e
institution Directory Open Access Journal
issn 2297-8739
language English
last_indexed 2024-03-09T15:51:16Z
publishDate 2022-12-01
publisher MDPI AG
record_format Article
series Separations
spelling doaj.art-232cfb35574c428d9ee59a446d99629e2023-11-24T17:59:53ZengMDPI AGSeparations2297-87392022-12-0191242610.3390/separations9120426Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity StudiesRiti Thapar Kapoor0Mohd Rafatullah1Ahmed Muteb Aljuwayid2Mohamed A. Habila3Saikh Mohammad Wabaidur4Mahboob Alam5Amity Institute of Biotechnology, Amity University Uttar Pradesh, Noida 201313, IndiaEnvironmental Technology Division, School of Industrial Technology, Universiti Sains Malaysia, Penang 11800, MalaysiaDepartment of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaDivision of Chemistry and Biotechnology, Dongguk University, 123 Dongdaero, Gyeongju-si 780714, Republic of KoreaPatent Blue (PB) dye removal from an aqueous medium was investigated using pineapple fruit peel biochar (PFPB). The presence of functional groups and surface characteristics of PFPB was studied using Fourier transform infrared spectra (FTIR) and scanning electron microscopy (SEM). A study was conducted to assess the pH effect, contact time, concentration of dye, biochar dose, speed of agitation, and temperature on removal of PB (Patent Blue) dye from an aqueous medium by PFPB. The highest 95% elimination of PB dye was reported at pH 2 by PFPB with 600 mg/L concentration of PB dye. Equilibrium studies divulged the favorable adsorption that followed the Langmuir isotherm with a monolayer uptake potential of 10.29 mg/g. Findings of kinetics disclosed that adsorption results were properly explained by the pseudo second-order model. The adsorption phenomenon was exothermic and spontaneous, as observed by thermodynamic variables. PFPB reflected a 37% uptake capacity of PB dye for up to five consecutive cycles in the adsorption and desorption study. A phytotoxicity study exhibited that PFPB-treated PB dye solution enhanced the growth of seedlings and biochemical constituents of lentils. The findings of the present study indicate the immense potential of pineapple fruit peel biochar for anionic dye removal from wastewater systems. Thus, pineapple fruit peel biochar can be utilized as a promising green sorbent for the elimination of Patent Blue dye in industrial effluents, as it is widely available and converts wastewater into reusable assets.https://www.mdpi.com/2297-8739/9/12/426<i>Ananas comosus</i>biocharPatent Bluephytotoxicity
spellingShingle Riti Thapar Kapoor
Mohd Rafatullah
Ahmed Muteb Aljuwayid
Mohamed A. Habila
Saikh Mohammad Wabaidur
Mahboob Alam
Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
Separations
<i>Ananas comosus</i>
biochar
Patent Blue
phytotoxicity
title Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
title_full Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
title_fullStr Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
title_full_unstemmed Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
title_short Removal of Patent Blue Dye Using <i>Ananas comosus</i>-Derived Biochar: Equilibrium, Kinetics, and Phytotoxicity Studies
title_sort removal of patent blue dye using i ananas comosus i derived biochar equilibrium kinetics and phytotoxicity studies
topic <i>Ananas comosus</i>
biochar
Patent Blue
phytotoxicity
url https://www.mdpi.com/2297-8739/9/12/426
work_keys_str_mv AT ritithaparkapoor removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies
AT mohdrafatullah removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies
AT ahmedmutebaljuwayid removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies
AT mohamedahabila removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies
AT saikhmohammadwabaidur removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies
AT mahboobalam removalofpatentbluedyeusingiananascomosusiderivedbiocharequilibriumkineticsandphytotoxicitystudies