Enthalpic interactions of glycine in aqueous urea solutions at 298.15K(甘氨酸在尿素水溶液中的焓对相互作用)
用LKB-2277精密微热量计测定了298.15K时甘氨酸在尿素水溶液（尿素的质量分数为0.05～0.40，以0.05递增）中的稀释焓，并根据McMillan-Mayer过量焓理论关联得到焓对作用系数.结果表明，甘氨酸的焓对作用系数与溶剂结构密切相关，其数值随尿素浓度的增大而增大，且在尿素高浓度区由负变为正....
| Main Authors: | , , |
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| Format: | Article |
| Language: | zho |
| Published: |
Zhejiang University Press
2000-11-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2000.27.6.623-627 |