Inter- and Intra-Molecular Organocatalysis of S<sub>N</sub>2 Fluorination by Crown Ether: Kinetics and Quantum Chemical Analysis

Inter- and Intra-Molecular Organocatalysis of S<sub>N</sub>2 Fluorination by Crown Ether: Kinetics and Quantum Chemical Analysis

We present the intra- and inter-molecular organocatalysis of S<sub>N</sub>2 fluorination using CsF by crown ether to estimate the efficacy of the promoter and to elucidate the reaction mechanism. The yields of intramolecular S<sub>N</sub>2 fluorination of the veratrole substr...

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Bibliographic Details
Main Authors: Young-Ho Oh, Wonhyuck Yun, Chul-Hee Kim, Sung-Woo Jang, Sung-Sik Lee, Sungyul Lee, Dong-Wook Kim
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Molecules
Subjects:
organocatalysis
S<sub>N</sub>2 fluorination
crown ether
quantum chemistry
Online Access:https://www.mdpi.com/1420-3049/26/10/2947

Internet

https://www.mdpi.com/1420-3049/26/10/2947

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