One‐Pot Synthesis of 2,5‐Furandicarboxylic Acid from 2‐Furoic Acid by a Pd‐catalyzed Bromination–Hydroxycarbonylation Tandem Reaction in Acetate Buffer

One‐Pot Synthesis of 2,5‐Furandicarboxylic Acid from 2‐Furoic Acid by a Pd‐catalyzed Bromination–Hydroxycarbonylation Tandem Reaction in Acetate Buffer

Abstract The one‐pot synthesis of 2,5‐furandicarboxylic acid from 2‐furoic acid with a yield of 57 % was achieved for the first time using a Pd‐catalyzed bromination‐hydroxycarbonylation tandem reaction in HOAc‐NaOAc buffer. This synthetic protocol shows major improvements compared to previously rep...

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Bibliographic Details
Main Authors: Yin‐Qing Yao, Kai‐Chun Zhao, Yi‐Ying Zhuang, Xiao‐Chao Chen, Prof. Dr. Yong Lu, Prof. Dr. Ye Liu
Format: Article
Language:English
Published: Wiley-VCH 2022-04-01
Series:ChemistryOpen
Subjects:
bromination
2,5-furandicarboxylic acid
2-furoic acid
hydroxycarbonylation
tandem reaction
Online Access:https://doi.org/10.1002/open.202100301

Internet

https://doi.org/10.1002/open.202100301

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