Regioselective Benzoylation of Diols and Carbohydrates by Catalytic Amounts of Organobase

Regioselective Benzoylation of Diols and Carbohydrates by Catalytic Amounts of Organobase

A novel metal-free organobase-catalyzed regioselective benzoylation of diols and carbohydrates has been developed. Treatment of diol and carbohydrate substrates with 1.1 equiv. of 1-benzoylimidazole and 0.2 equiv. of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in MeCN under mild conditions resulted in...

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Bibliographic Details
Main Authors: Yuchao Lu, Chenxi Hou, Jingli Ren, Xiaoting Xin, Hengfu Xu, Yuxin Pei, Hai Dong, Zhichao Pei
Format: Article
Language:English
Published: MDPI AG 2016-05-01
Series:Molecules
Subjects:
benzoylation
regioselectivity
DBU
benzoylimidazole
catalysis
Online Access:http://www.mdpi.com/1420-3049/21/5/641

Internet

http://www.mdpi.com/1420-3049/21/5/641

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