An Operative Electrostatic Slipping Mechanism along Macrocycle Flexibility Accelerates Guest Sliding during pseudo‐Rotaxane Formation

An Operative Electrostatic Slipping Mechanism along Macrocycle Flexibility Accelerates Guest Sliding during pseudo‐Rotaxane Formation

Abstract A pseudo‐rotaxane is a host−guest complex composed of a linear molecule encircled by a macrocyclic ring. These complexes can be assembled by sliding the host over the guest terminal groups. If there is a close match between the molecular volume of the flanking groups on the guest and the ca...

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Bibliographic Details
Main Authors: Dr. Aldo C. Catalán, Axel A. Loredo, Dr. Ruy Cervantes, Prof. Dr. Jorge Tiburcio
Format: Article
Language:English
Published: Wiley-VCH 2022-06-01
Series:ChemistryOpen
Subjects:
supramolecular chemistry
host−guest systems
kinetics
self-assembly
molecular recognition
Online Access:https://doi.org/10.1002/open.202200112

Internet

https://doi.org/10.1002/open.202200112

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