Crystal structure of cis-dichlorido(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III) (oxalato-κ2O1,O2)(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III) bis(perchlorate) from synchrotron data

Crystal structure of cis-dichlorido(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III) (oxalato-κ2O1,O2)(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III) bis(perchlorate) from synchrotron data

In the asymmetric unit of the title compound, [CrCl2(C10H24N4)][Cr(C2O4)(C10H24N4)](ClO4)2 (C10H24N4 = 1,4,8,11-tetraazacyclotetradecane, cyclam; C2O4 = oxalate, ox), there are two independent halves of the [CrCl2(cyclam)]+ and [Cr(ox)(cyclam)]+ cations, and one perchlorate anion. In the complex cat...

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Bibliographic Details
Main Authors: Dohyun Moon, Jong-Ha Choi
Format: Article
Language:English
Published: International Union of Crystallography 2016-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclam
synchrotron radiation
chromium(III) complex
chloride ligand
oxalato ligand
cis-V conformation
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016014134

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http://scripts.iucr.org/cgi-bin/paper?S2056989016014134

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