Electron-rotation coupling in UV photodissociation of aligned diatomics

We investigate the effect of electron-rotation coupling (R−Ω coupling) on fs UV photodissociation dynamics of aligned diatomic molecules. We consider the showcase of ground-state MgH^{+} (^{1}Σ^{+}) pumped by an fs IR pulse, which initiates rotational dynamics leading to field-free molecular alignme...

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Bibliographic Details
Main Authors: Yan Rong Liu, Victor Kimberg, Yong Wu, Jian Guo Wang, Oriol Vendrell, Song Bin Zhang
Format: Article
Language:English
Published: American Physical Society 2022-01-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.4.013066