Reduction of 2,2′-Bipyridine by Quasi-Linear 3d-Metal(I) Silylamides—A Structural and Spectroscopic Study

Reduction of 2,2′-Bipyridine by Quasi-Linear 3d-Metal(I) Silylamides—A Structural and Spectroscopic Study

Quasi-linear anionic 3d-metal(I) silylamides are a new and promising class of molecules. Due to their highly negative reduction potential we wanted to test their capability to reduce substrates under coordination of their monoanionic radicaloid form. In a proof of principle study, we present the res...

Full description

Bibliographic Details
Main Authors: Igor Müller, Christian Schneider, Clemens Pietzonka, Florian Kraus, C. Gunnar Werncke
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Inorganics
Subjects:
oxidation state +1
3d-metals
two-coordinate complexes
electron transfer
n-ligands
Online Access:https://www.mdpi.com/2304-6740/7/10/117

Internet

https://www.mdpi.com/2304-6740/7/10/117

Similar Items