Exploring the Limits of Reactivity of <i>N</i>-Methyl-1,2,4-triazoline-3,5-dione (MeTAD) with Disubstituted Bicycloalkadienes in the Homo-Diels–Alder Reaction

The [2+2+2] cycloaddition (homo-Diels–Alder reaction) of <i>N</i>-substituted 1,2,4-triazoline-3,5-diones (TADs) with bicycloalkadienes produces strained heterocyclic compounds. A reaction with the unsubstituted dienes occurs readily to produce only the expected homo-Diels–Alder adducts....

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Bibliographic Details
Main Authors: Gary W. Breton, Kenneth L. Martin
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Organics
Subjects:
Online Access:https://www.mdpi.com/2673-401X/4/1/2