Rhodium(III)-catalyzed chelation-assisted ortho-selective carbon−hydrogen alkylation of phenols with diazocarbonyl compounds involving a carbene migratory insertion process

An efficient and convenient rhodium(III)-catalyzed chelation-assisted ortho-selective carbon−hydrogen bond alkylation of phenols treated with readily available diazocarbonyl compounds as the alkyl source has been described. Migratory carbene insertion represents the principal step to realize this ca...

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Bibliographic Details
Main Authors: Lin-Yu Jiao, Zi-Hui Ning, Xiao-Mei Yin, Qian Hong, Shanshan Liu, Xiao-Xun Ma
Format: Article
Language:English
Published: Elsevier 2021-03-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736721000017