Rhodium(III)-catalyzed chelation-assisted ortho-selective carbon−hydrogen alkylation of phenols with diazocarbonyl compounds involving a carbene migratory insertion process
An efficient and convenient rhodium(III)-catalyzed chelation-assisted ortho-selective carbon−hydrogen bond alkylation of phenols treated with readily available diazocarbonyl compounds as the alkyl source has been described. Migratory carbene insertion represents the principal step to realize this ca...
Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
Published: |
Elsevier
2021-03-01
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Series: | Catalysis Communications |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736721000017 |