Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching

Abstract Electric conductivity in metal-organic frameworks (MOFs) follows either a band-like or a redox-hopping charge transport mechanism. While conductivity by the band-like mechanism is theoretically and experimentally well established, the field has struggled to experimentally demonstrate redox...

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Bibliographic Details
Main Authors: Jingguo Li, Amol Kumar, Ben A. Johnson, Sascha Ott
Format: Article
Language:English
Published: Nature Portfolio 2023-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-40110-6