Novel Synthesis Methods of New Imidazole-Containing Coordination Compounds Tc(IV, V, VII)—Reaction Mechanism, Xrd and Hirshfeld Surface Analysis

Novel Synthesis Methods of New Imidazole-Containing Coordination Compounds Tc(IV, V, VII)—Reaction Mechanism, Xrd and Hirshfeld Surface Analysis

In this work, we have proposed two new methods for the synthesis of [TcO<sub>2</sub>L<sub>4</sub>]<sup>+</sup> (where L = imidazole (Im), methylimidazole (MeIm)) complexes using thiourea (Tu) and Sn(II) as the reducing agents. The main and by-products of the react...

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Bibliographic Details
Main Authors: Mikhail Alexandrovich Volkov, Anton Petrovich Novikov, Mikhail Semenovich Grigoriev, Alexander Mikhailovich Fedoseev, Konstantin Eduardovich German
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:International Journal of Molecular Sciences
Subjects:
technetium
imidazole
technetyl
XRD-analysis
Hirshfeld surface analysis
π-interactions
Online Access:https://www.mdpi.com/1422-0067/23/16/9461

Internet

https://www.mdpi.com/1422-0067/23/16/9461

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