Synthesis of a Stable Primary-Alkyl-Substituted Selenenyl Iodide and Its Hydrolytic Conversion to the Corresponding Selenenic Acid

Synthesis of a Stable Primary-Alkyl-Substituted Selenenyl Iodide and Its Hydrolytic Conversion to the Corresponding Selenenic Acid

A primary-alkyl-substituted selenenyl iodide was successfully synthesized through oxidative iodination of a selenol with N-iodosuccinimide by taking advantage of a cavity-shaped steric protection group. The selenenyl iodide exhibited high thermal stability and remained unchanged upon heating at 100...

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Bibliographic Details
Main Authors: Shohei Sase, Ryo Kakimoto, Ryutaro Kimura, Kei Goto
Format: Article
Language:English
Published: MDPI AG 2015-12-01
Series:Molecules
Subjects:
selenenyl iodide
selenenic acid
hydrolysis
kinetic stabilization
iodothyronine deiodinase
Online Access:http://www.mdpi.com/1420-3049/20/12/19773

Internet

http://www.mdpi.com/1420-3049/20/12/19773

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