Crystal structure of imidazo[1,5-a]pyridinium-based hybrid salt (C13H12N3)2[MnCl4]

Crystal structure of imidazo[1,5-a]pyridinium-based hybrid salt (C13H12N3)2[MnCl4]

A new organic–inorganic hybrid salt [L]2[MnCl4] (I) where L+ is the 2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridinium cation, is built of discrete organic cations and tetrachloridomanganate(II) anions. The L+ cation was formed in situ in the oxidative cyclocondensation of 2-pyridinecarbaldehyde and...

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Bibliographic Details
Main Authors: Olga Yu. Vassilyeva, Elena A. Buvaylo, Vladimir N. Kokozay, Svitlana R. Petrusenko, Andrii K. Melnyk, Brian W. Skelton
Format: Article
Language:English
Published: International Union of Crystallography 2020-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
mnii
organic-inorganic hybrid
tetrahalometallate
π–π stacking
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020001425

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http://scripts.iucr.org/cgi-bin/paper?S2056989020001425

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