Total Syntheses and Stereochemical Assignment of Acremolides A and B

Total Syntheses and Stereochemical Assignment of Acremolides A and B

The absolute stereochemical configurations of acremolides A and B were predicted by a biochemistry-based rule and unambiguously confirmed through their total syntheses. The features of the total syntheses include sequential Krische’s Ir-catalyzed crotylation, Brown’s borane-mediated crotylation, Mit...

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Bibliographic Details
Main Authors: Yi Xiao, Junyang Liu, Yangyang Jiang, Yian Guo, Tao Ye
Format: Article
Language:English
Published: MDPI AG 2024-07-01
Series:Molecules
Subjects:
total syntheses
natural products
asymmetric crotylation
acremolide
Online Access:https://www.mdpi.com/1420-3049/29/15/3599

Internet

https://www.mdpi.com/1420-3049/29/15/3599

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