The selective electrochemical fluorination of S-alkyl benzothioate and its derivatives

The selective electrochemical fluorination of S-alkyl benzothioate and its derivatives

We herein report that the regioselective anodic fluorination of S-alkyl benzothioate and its derivatives in various aprotic solvents using Et3N·nHF (n = 3–5) and Et4NF·nHF (n = 3–5) as supporting electrolyte and a fluorine source successfully provided the corresponding α-fluorinated products in mode...

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Bibliographic Details
Main Authors: Shunsuke Kuribayashi, Tomoyuki Kurioka, Shinsuke Inagi, Ho-Jung Lu, Biing-Jiun Uang, Toshio Fuchigami
Format: Article
Language:English
Published: Beilstein-Institut 2018-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
anodic cyclization
diastereoselective fluorination
electrosynthesis
fluorobenzothiophenone
selective fluorination
Online Access:https://doi.org/10.3762/bjoc.14.27

Internet

https://doi.org/10.3762/bjoc.14.27

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