Giant Heterometallic [Mn36Ni4]0/2− and [Mn32Co8] “Loops-of-Loops-and-Supertetrahedra” Molecular Aggregates

Giant Heterometallic [Mn36Ni4]0/2− and [Mn32Co8] “Loops-of-Loops-and-Supertetrahedra” Molecular Aggregates

We report the synthesis, crystal structures and magnetic properties of the giant heterometallic [Mn36Ni4]2−/0 (compounds 1, 2)/[Mn32Co8] (compound 3) “loops-of-loops-and-supertetrahedra” molecular aggregates and of a [Mn2Ni6]2+ compound (cation of 4) that is structurally related with the cation co-c...

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Bibliographic Details
Main Authors: Maria Charalambous, Eleni E. Moushi, Tu N. Nguyen, Constantina Papatriantafyllopoulou, Vassilios Nastopoulos, George Christou, Anastasios J. Tasiopoulos
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-03-01
Series:Frontiers in Chemistry
Subjects:
Mn
heterometallic clusters
diols
magnetic properties
crystal structures
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00096/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00096/full

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