Palladium-Catalyzed Acetoxylation of γ-Dehydro-aryl-himachalene: The Synthesis of a Novel Allylic Acetoxylated Sesquiterpene and a π-Allyl Palladium(II) Complex

Palladium-Catalyzed Acetoxylation of γ-Dehydro-aryl-himachalene: The Synthesis of a Novel Allylic Acetoxylated Sesquiterpene and a π-Allyl Palladium(II) Complex

Allylic oxygenated derivatives of himachalenes are highly valued molecules due to their potential applications in perfumery, cosmetics, and pharmaceuticals. Previous attempts at catalyzed allylic oxidation of himachalenes led to the formation of a very stable η<sup>3</sup>-allyl palladiu...

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Bibliographic Details
Main Authors: Issam Louchachha, Abdelmajid Faris, Youssef Edder, Ali Hasnaoui, Anna Kozakiewicz-Piekarz, Abdelkarim Ait Mansour, Brahim Boualy, Rachid Salghi, Khalil Azzaoui, Rachid Sabbahi, Ashwag S. Alanazi, Mohamed Hefnawy, Belkheir Hammouti, Abdallah Karim, Mustapha Ait Ali
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Molecules
Subjects:
sesquiterpenes
palladium-catalyzed acetoxylation
himachalenes
η<sup>3</sup>-allyl palladium complex
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/29/21/5040

Internet

https://www.mdpi.com/1420-3049/29/21/5040

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