Solid State Phosphorescence Enhancement of Pt<sup>II</sup>-Based Emitters via Combination of π-Hole(Isocyano Group)⋅⋅⋅ d<sub>z</sub><sup>2</sup>[Pt<sup>II</sup>] and I···Cl Halogen-Bonding Interactions

Solid State Phosphorescence Enhancement of Pt<sup>II</sup>-Based Emitters via Combination of π-Hole(Isocyano Group)⋅⋅⋅ d<sub>z</sub><sup>2</sup>[Pt<sup>II</sup>] and I···Cl Halogen-Bonding Interactions

The Pt<sup>II</sup> isocyanide complex [Pt(ppy)Cl(CNC<sub>6</sub>H<sub>4</sub>-C≡C-Ph)] (<b>1</b>, Hppy=2-phenylpyridine) was co-crystallized with 1,4-diiodotetrafluorobenzene (1,4-DITFB), yielding <b>1</b>·½(1,4-DITFB) adduct. The I···Cl h...

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Bibliographic Details
Main Authors: Svetlana A. Katkova, Elina V. Antonova, Anna M. Cheranyova, Daniil M. Ivanov, Mikhail A. Kinzhalov
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Inorganics
Subjects:
isocyanide ligands
π-hole interactions
noncovalent interactions
halogen bonding
luminescence
platinum(II) complexes
Online Access:https://www.mdpi.com/2304-6740/11/10/403

Internet

https://www.mdpi.com/2304-6740/11/10/403

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