Synthesis, Characterization, and Catalytic Exploration of Mononuclear Mo(VI) Dioxido Complexes of (<i>Z</i>)-1-<i>R</i>-2-(4′,4′-Dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ates

Synthesis, Characterization, and Catalytic Exploration of Mononuclear Mo(VI) Dioxido Complexes of (<i>Z</i>)-1-<i>R</i>-2-(4′,4′-Dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ates

The coordination chemistry of the title ligands with Mo metal centers was investigated. Thus, the synthesis and characterization (NMR, X-ray diffraction) of four mononuclear formally Mo(6+) complexes of (<i>Z</i>)-1-<i>R</i>-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ate...

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Bibliographic Details
Main Authors: Anna Petrov, Jeanette A. Adjei, Alan J. Lough, R. Stephen Wylie, Robert A. Gossage
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Molecules
Subjects:
oxazoline-enolate chelates
molybdenum(6+) oxide complexes
X-ray structure determination
benzoin oxidation
semi-empirical PM6(tm) calculations
Online Access:https://www.mdpi.com/1420-3049/27/4/1309

Internet

https://www.mdpi.com/1420-3049/27/4/1309

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