Sila-spirocyclization involving unstrained C(sp3)−Si bond cleavage

Abstract C − Si Bond cleavage is one of the key elemental steps for a wide variety of silicon-based transformations. However, the cleavage of unstrained Si−C(sp3) bonds catalyzed by transition metal are still in their infancy. They generally involve the insertion of a M − C(sp2) species into the C −...

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Bibliographic Details
Main Authors: Yufeng Shi, Xiaonan Shi, Jinyu Zhang, Ying Qin, Bo Li, Dongbing Zhao
Format: Article
Language:English
Published: Nature Portfolio 2022-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-34466-4