Presolvated Electron Reactions with Methyl Acetoacetate: Electron Localization, Proton-Deuteron Exchange, and H-Atom Abstraction

Presolvated Electron Reactions with Methyl Acetoacetate: Electron Localization, Proton-Deuteron Exchange, and H-Atom Abstraction

Radiation-produced electrons initiate various reaction processes that are important to radiation damage to biomolecules. In this work, the site of attachment of the prehydrated electrons with methyl acetoacetate (MAA, CH3-CO-CH2-COOCH3) at 77 K and subsequent reactions of the anion radical (CH3-CO•−...

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Detaylı Bibliyografya
Asıl Yazarlar: Alex Petrovici, Amitava Adhikary, Anil Kumar, Michael D. Sevilla
Materyal Türü: Makale
Dil:English
Baskı/Yayın Bilgisi: MDPI AG 2014-09-01
Seri Bilgileri:Molecules
Konular:
prehydrated electron
anion radical
proton-deuteron exchange
H-atom abstraction
Online Erişim:http://www.mdpi.com/1420-3049/19/9/13486

Internet

http://www.mdpi.com/1420-3049/19/9/13486

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