(1<i>S</i>,5<i>R</i>)-6,6-Dimethyl-4-(((1<i>S</i>,2<i>S</i>,5<i>S</i>)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

(1<i>S</i>,5<i>R</i>)-6,6-Dimethyl-4-(((1<i>S</i>,2<i>S</i>,5<i>S</i>)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yie...

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Bibliographic Details
Main Authors: Oleg V. Ardashov, Dina V. Korchagina, Irina Yu. Bagryanskaya, Konstantin P. Volcho, Nariman F. Salakhutdinov
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Molbank
Subjects:
verbenone
dimerization
extended enolate
Michael addition
Online Access:https://www.mdpi.com/1422-8599/2022/4/M1465

Internet

https://www.mdpi.com/1422-8599/2022/4/M1465

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