Multinuclear Variable Temperature NMR Studies on Cyanide, Water and Hydroxyl Group Scrambling on Halogenation of K2[Pt(CN)4] and Related Reactions
195Pt and 1H NMR has been used to show that addition of chlorine and bromine to [Pt(CN)4]2_ in presence of perchloric acid in water results in cyanide and water scrambling with formation of eleven complexes of the type [Pt(CN)4-nCl(H2O)n+1](n-1)+ (n=0, 1, 2, 3, 4). Addition of NBu4OH to this solutio...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1998-12-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10297_6fb062bf13c3b3bc764aead0d1eabc46.pdf |