In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid
The adoption of plant-derived natural products to synthesize metal nanoparticles and their complexes has the advantages of mild reaction conditions, environmental protection, sustainability and simple operation compared with traditional physical or chemical synthesis methods. Herein, silver nanopart...
Main Authors: | , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Frontiers Media S.A.
2022-04-01
|
Series: | Frontiers in Chemistry |
Subjects: | |
Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2022.905781/full |
_version_ | 1818009944882937856 |
---|---|
author | Yunhui Bao Chunlian Tian Huazhong Yu Huazhong Yu Jian He Jian He Ke Song Ke Song Jie Guo Jie Guo Xianwu Zhou Xianwu Zhou Ou Zhuo Shima Liu Shima Liu |
author_facet | Yunhui Bao Chunlian Tian Huazhong Yu Huazhong Yu Jian He Jian He Ke Song Ke Song Jie Guo Jie Guo Xianwu Zhou Xianwu Zhou Ou Zhuo Shima Liu Shima Liu |
author_sort | Yunhui Bao |
collection | DOAJ |
description | The adoption of plant-derived natural products to synthesize metal nanoparticles and their complexes has the advantages of mild reaction conditions, environmental protection, sustainability and simple operation compared with traditional physical or chemical synthesis methods. Herein, silver nanoparticles (AgNPs) were in situ synthesized on the surface of graphene oxide (GO) by a “one-pot reaction” to prepare graphene oxide-silver nanoparticles composite (GO-AgNPs) based on using AgNO3 as the precursor of AgNPs and gallic acid (GA) as the reducing agent and stabilizer. The size and morphology of GO-AgNPs were characterized by ultraviolet-visible spectrophotometer (Uv-vis), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), X-ray diffractometer (XRD) and dynamic light scattering (DLS). The effects of pH, temperature, time and material ratio on the synthesis of GO-AgNPs were investigated experimentally. The results showed that ideal GO-AgNPs could be prepared under the conditions of pH = 9, 45°C, 2 h and the 2:1 of molar ratio of AgNO3 to GA. The AgNPs within GO-AgNPs are highly crystalline spherical particles with moderate density on the surface of GO, and the size of AgNPs is relatively uniform and determined to be about 8.19 ± 4.21 nm. The research results will provide new ideas and references for the green synthesis of metal nanoparticles and their complexes using plant-derived natural products as the reducing agent and stabilizer. |
first_indexed | 2024-04-14T05:49:15Z |
format | Article |
id | doaj.art-2dc6112219814d1f9d680d952cce4830 |
institution | Directory Open Access Journal |
issn | 2296-2646 |
language | English |
last_indexed | 2024-04-14T05:49:15Z |
publishDate | 2022-04-01 |
publisher | Frontiers Media S.A. |
record_format | Article |
series | Frontiers in Chemistry |
spelling | doaj.art-2dc6112219814d1f9d680d952cce48302022-12-22T02:09:10ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-04-011010.3389/fchem.2022.905781905781In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic AcidYunhui Bao0Chunlian Tian1Huazhong Yu2Huazhong Yu3Jian He4Jian He5Ke Song6Ke Song7Jie Guo8Jie Guo9Xianwu Zhou10Xianwu Zhou11Ou Zhuo12Shima Liu13Shima Liu14Key Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaKey Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, ChinaCollege of Chemistry and Chemical Engineering, Jishou University, Jishou, ChinaThe adoption of plant-derived natural products to synthesize metal nanoparticles and their complexes has the advantages of mild reaction conditions, environmental protection, sustainability and simple operation compared with traditional physical or chemical synthesis methods. Herein, silver nanoparticles (AgNPs) were in situ synthesized on the surface of graphene oxide (GO) by a “one-pot reaction” to prepare graphene oxide-silver nanoparticles composite (GO-AgNPs) based on using AgNO3 as the precursor of AgNPs and gallic acid (GA) as the reducing agent and stabilizer. The size and morphology of GO-AgNPs were characterized by ultraviolet-visible spectrophotometer (Uv-vis), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), X-ray diffractometer (XRD) and dynamic light scattering (DLS). The effects of pH, temperature, time and material ratio on the synthesis of GO-AgNPs were investigated experimentally. The results showed that ideal GO-AgNPs could be prepared under the conditions of pH = 9, 45°C, 2 h and the 2:1 of molar ratio of AgNO3 to GA. The AgNPs within GO-AgNPs are highly crystalline spherical particles with moderate density on the surface of GO, and the size of AgNPs is relatively uniform and determined to be about 8.19 ± 4.21 nm. The research results will provide new ideas and references for the green synthesis of metal nanoparticles and their complexes using plant-derived natural products as the reducing agent and stabilizer.https://www.frontiersin.org/articles/10.3389/fchem.2022.905781/fullgreen synthesisgallic acidsilver nanoparticlesgraphene oxidenatural products |
spellingShingle | Yunhui Bao Chunlian Tian Huazhong Yu Huazhong Yu Jian He Jian He Ke Song Ke Song Jie Guo Jie Guo Xianwu Zhou Xianwu Zhou Ou Zhuo Shima Liu Shima Liu In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid Frontiers in Chemistry green synthesis gallic acid silver nanoparticles graphene oxide natural products |
title | In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid |
title_full | In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid |
title_fullStr | In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid |
title_full_unstemmed | In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid |
title_short | In Situ Green Synthesis of Graphene Oxide-Silver Nanoparticles Composite with Using Gallic Acid |
title_sort | in situ green synthesis of graphene oxide silver nanoparticles composite with using gallic acid |
topic | green synthesis gallic acid silver nanoparticles graphene oxide natural products |
url | https://www.frontiersin.org/articles/10.3389/fchem.2022.905781/full |
work_keys_str_mv | AT yunhuibao insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT chunliantian insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT huazhongyu insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT huazhongyu insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT jianhe insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT jianhe insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT kesong insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT kesong insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT jieguo insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT jieguo insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT xianwuzhou insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT xianwuzhou insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT ouzhuo insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT shimaliu insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid AT shimaliu insitugreensynthesisofgrapheneoxidesilvernanoparticlescompositewithusinggallicacid |