Methalloporphirins Catalyze Regio and Chemoselective Silylation of Hydroxy Groups with Hexamethyldisilazane (HMDS)
Metalloporphirins; Cu(TPP), Mn(TPP)Cl, CO(TPP), Fe(TPP)Cl, zn(TPP) and Mn(OBP)Cl catalyze region and chemoselective silylation of hydroxyl groups with HMDS. Fe(TPP)Cl is the most effective catalyst and silylation occurs immediately in its presence at room temperature.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1996-12-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10431_b39f4095ca84e6612982551f5e69959a.pdf |