The Reactivity of Azidonitrobenzofuroxans towards 1,3-Dicarbonyl Compounds: Unexpected Formation of Amino Derivative via the Regitz Diazo Transfer and Tautomerism Study

The Reactivity of Azidonitrobenzofuroxans towards 1,3-Dicarbonyl Compounds: Unexpected Formation of Amino Derivative via the Regitz Diazo Transfer and Tautomerism Study

Herein, we report on the reaction of nitro-substituted azidobenzofuroxans with 1,3-dicarbonyl compounds in basic media. The known reactions of benzofuroxans and azidofuroxans with 1,3-dicarbonyl compounds in the presence of bases are the 1,3-dipolar cycloaddition and the Beirut reaction. In contrast...

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Bibliographic Details
Main Authors: Elena Chugunova, Almir Gazizov, Daut Islamov, Alexander Burilov, Alena Tulesinova, Sergey Kharlamov, Victor Syakaev, Vasily Babaev, Nurgali Akylbekov, Nurbol Appazov, Konstantin Usachev, Rakhmetulla Zhapparbergenov
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:International Journal of Molecular Sciences
Subjects:
benzofuroxan
1,3-dicarbonyl compounds
Regitz diazo transfer
tautomerism
Online Access:https://www.mdpi.com/1422-0067/22/17/9646

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https://www.mdpi.com/1422-0067/22/17/9646

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