Cationic Pd(II)-catalyzed C–H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies

Cationic Pd(II)-catalyzed C–H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies

Cationic palladium(II) complexes have been found to be highly reactive towards aromatic C–H activation of arylureas at room temperature. A commercially available catalyst [Pd(MeCN)4](BF4)2 or a nitrile-free cationic palladium(II) complex generated in situ from the reaction of Pd(OAc)2 and HBF4, effe...

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Bibliographic Details
Main Authors: Takashi Nishikata, Alexander R. Abela, Shenlin Huang, Bruce H. Lipshutz
Format: Article
Language:English
Published: Beilstein-Institut 2016-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
arylation
cationic palladium
C–H functionalization
green chemistry
olefination
Online Access:https://doi.org/10.3762/bjoc.12.99

Internet

https://doi.org/10.3762/bjoc.12.99

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