Sulfonylimino Group Transfer Reaction Using Imino-λ3-iodanes with I2 as Catalyst Under Metal-free Conditions

Sulfonylimino Group Transfer Reaction Using Imino-λ3-iodanes with I2 as Catalyst Under Metal-free Conditions

A new practical procedure of imination for sulfide has been developed. The treatment of (N-tosylimino)-phenyl-λ3-iodane, PhINTs, with various sulfides in the presence of a catalytic amount of I2 under metal-free conditions affords the corresponding N-tosylsulfilimine compounds with modera...

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Bibliographic Details
Main Authors: Akira Yoshimura, Cody L. Makitalo, Melissa E. Jarvi, Michael T. Shea, Pavel S. Postnikov, Gregory T. Rohde, Viktor V. Zhdankin, Akio Saito, Mekhman S. Yusubov
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Molecules
Subjects:
iminoiodanes
imination
sulfide
sulfilimine
phosphine
iminophosphorane
amidyl radical
catalytic cycle
iodine
Online Access:http://www.mdpi.com/1420-3049/24/5/979

Internet

http://www.mdpi.com/1420-3049/24/5/979

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