Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template

Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4− ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.

Библиографические подробности
Главные авторы: Laura Gasque, Sylvain Bernès, Juan Olguín
Формат: Статья
Язык:English
Опубликовано: MDPI AG 2012-09-01
Серии:Crystals
Предметы:
Online-ссылка:http://www.mdpi.com/2073-4352/2/3/1357