Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4− ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-09-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4352/2/3/1357 |
| _version_ | 1798003541342683136 |
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| author | Laura Gasque Sylvain Bernès Juan Olguín |
| author_facet | Laura Gasque Sylvain Bernès Juan Olguín |
| author_sort | Laura Gasque |
| collection | DOAJ |
| description | Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4− ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding. |
| first_indexed | 2024-04-11T12:09:11Z |
| format | Article |
| id | doaj.art-2f752e22e88e4b4bb27fff789f315197 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T12:09:11Z |
| publishDate | 2012-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-2f752e22e88e4b4bb27fff789f3151972022-12-22T04:24:39ZengMDPI AGCrystals2073-43522012-09-01231357136510.3390/cryst2031357Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine TemplateLaura GasqueSylvain BernèsJuan OlguínTwo dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4− ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.http://www.mdpi.com/2073-4352/2/3/1357copperdiazecinehydrogen bond |
| spellingShingle | Laura Gasque Sylvain Bernès Juan Olguín Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template Crystals copper diazecine hydrogen bond |
| title | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_full | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_fullStr | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_full_unstemmed | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_short | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_sort | fluoride ion as ligand and hydrogen bond acceptor crystal structures of two dinuclear cuii complexes built on a diazecine template |
| topic | copper diazecine hydrogen bond |
| url | http://www.mdpi.com/2073-4352/2/3/1357 |
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