Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films

IR measurements were carried out on both amorphous and polycrystalline silicon samples deposited by PECVDon glass substrate. The transition from amorphous to polycrystalline phase was achieved by increasing dilution of silaneplasma at the deposition process. The samples were found to be mixed phase...

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Main Author: Jarmila Mullerova
Format: Article
Language:English
Published: VSB-Technical University of Ostrava 2006-01-01
Series:Advances in Electrical and Electronic Engineering
Subjects:
Online Access:http://advances.utc.sk/index.php/AEEE/article/view/228
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author Jarmila Mullerova
author_facet Jarmila Mullerova
author_sort Jarmila Mullerova
collection DOAJ
description IR measurements were carried out on both amorphous and polycrystalline silicon samples deposited by PECVDon glass substrate. The transition from amorphous to polycrystalline phase was achieved by increasing dilution of silaneplasma at the deposition process. The samples were found to be mixed phase materials. Commonly, infrared spectra ofhydrogenated silicon thin films yield information about microstructure, hydrogen content and hydrogen bonding to silicon. Inthis paper, additional understanding was retrieved from infrared response. Applying standard optical laws, effective mediatheory and Clausius-Mossoti approach concerning the Si-Si and Si-H bonds under IR irradiation as individual oscillators,refractive indices in the long wavelength limit, crystalline, amorphous and voids volume fractions and the mass density of thefilms were determined. The mass density was found to decrease with increasing crystalline volume fraction, which can beattributed to the void-dominated mechanism of network formation.
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spelling doaj.art-2f77392b079a42fcb465f2c95e87a0d42023-05-14T20:50:05ZengVSB-Technical University of OstravaAdvances in Electrical and Electronic Engineering1336-13761804-31192006-01-0151354357257Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin FilmsJarmila MullerovaIR measurements were carried out on both amorphous and polycrystalline silicon samples deposited by PECVDon glass substrate. The transition from amorphous to polycrystalline phase was achieved by increasing dilution of silaneplasma at the deposition process. The samples were found to be mixed phase materials. Commonly, infrared spectra ofhydrogenated silicon thin films yield information about microstructure, hydrogen content and hydrogen bonding to silicon. Inthis paper, additional understanding was retrieved from infrared response. Applying standard optical laws, effective mediatheory and Clausius-Mossoti approach concerning the Si-Si and Si-H bonds under IR irradiation as individual oscillators,refractive indices in the long wavelength limit, crystalline, amorphous and voids volume fractions and the mass density of thefilms were determined. The mass density was found to decrease with increasing crystalline volume fraction, which can beattributed to the void-dominated mechanism of network formation.http://advances.utc.sk/index.php/AEEE/article/view/228infraredcristallinemicrostructure.
spellingShingle Jarmila Mullerova
Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
Advances in Electrical and Electronic Engineering
infrared
cristalline
microstructure.
title Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
title_full Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
title_fullStr Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
title_full_unstemmed Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
title_short Infrared Insight into the Network of Hydrogenated Amorphous and Polycrystalline Silicon thin Films
title_sort infrared insight into the network of hydrogenated amorphous and polycrystalline silicon thin films
topic infrared
cristalline
microstructure.
url http://advances.utc.sk/index.php/AEEE/article/view/228
work_keys_str_mv AT jarmilamullerova infraredinsightintothenetworkofhydrogenatedamorphousandpolycrystallinesiliconthinfilms