Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade

Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade

We previously showed that the regio- and stereoselectivity in terpene-forming reactions are determined by the conformations of the carbocation intermediates, which reflect the initial conformation of the substrate, geranylfarnesyl diphosphate (GFPP). However, it remains unclear how the initial confo...

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Bibliographic Details
Main Authors: Hajime Sato, Takaaki Mitsuhashi, Mami Yamazaki, Ikuro Abe, Masanobu Uchiyama
Format: Article
Language:English
Published: Beilstein-Institut 2019-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
biosynthesis
carbocation
DFT
substrate recognition
terpene cyclase
Online Access:https://doi.org/10.3762/bjoc.15.184

Internet

https://doi.org/10.3762/bjoc.15.184

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