Ruthenium and iron complexes with benzotriazole and benzimidazole derivatives as simple models for proton-coupled electron transfer systems

Iron and ruthenium complexes of the type [M-LH]n (where M = RuII,III(NH3)5(2+,3+), RuII,III(edta)2-,- [edta = ethylenedinitrilotetraacetate], or FeII,III(CN)5(3-,2-) and LH = benzotriazole or benzimidazole) were prepared and characterized in aqueous solutions by means of electrochemical and spectroe...

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Bibliographic Details
Main Authors: Rocha Reginaldo C., Rein Francisca N., Toma Henrique E.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2001-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000200018