Synthesis, Characterization and Theoretical Calculations of Novel Five Membered Rings Containing Phosphorus and Arsenic Atoms

The synthesis of two new arsadiphospholes of formula (AsP2C2Bu t2 )CH(SiMe3)2, from 4-arsa-1,2-diphosphacyclopentadienyl and 2-arsa-1,4-diphosphacyclopentadienyl ring anions are reported together with their characterization by 31P NMR. Ab initio calculations at the MP2/6-31G(d) level of theory were...

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Bibliographic Details
Main Authors: Rocha Willian R., Duarte Leopoldo W. M., Almeida Wagner B. De, Caliman Vinicius
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2002-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000500009