Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe<sub>2</sub>(CO)<sub>4</sub>(κ<sup>2</sup>-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene)

Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe<sub>2</sub>(CO)<sub>4</sub>(κ<sup>2</sup>-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene)

Addition of the bulky redox-active diphosphine 1,8-bis(diphenylphosphino)naphthalene (dppn) to [Fe<sub>2</sub>(CO)<sub>6</sub>(&#181;-edt)] (<b>1</b>) (edt = 1,2-ethanedithiolate) affords [Fe<sub>2</sub>(CO)<sub>4</sub>(&#954;<su...

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Bibliographic Details
Main Authors: Shishir Ghosh, Shahed Rana, Nathan Hollingsworth, Michael G. Richmond, Shariff E. Kabir, Graeme Hogarth
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Inorganics
Subjects:
hydrogenase biomimetics
dithiolate
proton-reduction
dppn
redox-active
Online Access:https://www.mdpi.com/2304-6740/6/4/122

Internet

https://www.mdpi.com/2304-6740/6/4/122

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