The unusual quadruple bonding of nitrogen in ThN

Abstract Nitrogen has five valence electrons and can form a maximum of three shared electron-pair bonds to complete its octet, which suggests that its maximum bond order is three. With a joint anion photoelectron spectroscopy and quantum chemistry investigation, we report herein that nitrogen presen...

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Bibliographic Details
Main Authors: Zejie Fei, Jia-Qi Wang, Rulin Tang, Yuzhu Lu, Changcai Han, Yongtian Wang, Jing Hong, Changwu Dong, Han-Shi Hu, Xiao-Gen Xiong, Chuangang Ning, Hongtao Liu, Jun Li
Format: Article
Language:English
Published: Nature Portfolio 2023-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-43208-z