Two Model Compounds to Investigate the Gear Effect: 2,3-Dialkyl-Bicyclo[2.2.1]-Heptane and 2,3-Dialkyl-Bicyclo[2.2.2]-Octane
Compounds I, II and III, were used as models resembling gear systems (bods connecting CR3 groups to the skeletal molecule are parallel) in surveying the potential energy surface for their internal rotation. The magnitude of the barriers calculated for averaging the NMR signals, placed these compound...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1989-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_12265_d41d8cd98f00b204e9800998ecf8427e.pdf |