Template-Free Synthesis of a Phenanthroline-Containing [2]Rotaxane: A Reversible pH-Controllable Molecular Switch

Template-Free Synthesis of a Phenanthroline-Containing [2]Rotaxane: A Reversible pH-Controllable Molecular Switch

The synthesis of symmetric and asymmetric rotaxanes consisting of neutral axle and ring components without ionic templates is necessary for applications in molecular sensors and molecular switches. A phenanthroline-containing symmetric [2]rotaxane was newly synthesized by inducing hydrogen bonding a...

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Bibliographic Details
Main Authors: Masahiro Muraoka, Kakeru Aoyama, Sae Fujihara, Risa Yamane, Ichiro Hisaki, Mikiji Miyata, Michihisa Murata, Yohji Nakatsuji
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Symmetry
Subjects:
rotaxane
interlocked molecule
molecular switch
acid–base response
Online Access:https://www.mdpi.com/2073-8994/11/9/1137

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https://www.mdpi.com/2073-8994/11/9/1137

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