N-Aryl-substituted 5-aza-2,8-dioxasilabicyclo[3.3.01.5]octanes: syntheses, molecular structures, DFT calculations and cyclovoltammetric studies

N-Aryl-substituted 5-aza-2,8-dioxasilabicyclo[3.3.01.5]octanes: syntheses, molecular structures, DFT calculations and cyclovoltammetric studies

The reaction of the silanes X2SiCl2 (X=H, Cl) with the dilithium salts of N-phenyldiethanolamine (1) and N-4-fluorophenyl-di-(2-dimethylpropan-2-ol)amine (2), respectively, gave the novel 5-aza-2,8-dioxasilabicyclo[3.3.01.5]octanes RN(CH2CR′2O)2SiX2 (3, R=Ph, R′=X=H; 4, R=Ph, R′=H, X=Cl; 5, R=4-FC6H...

Full description

Bibliographic Details
Main Authors: Lutter Michael, Iovkova-Berends Ljuba, Dietz Christina, Jouikov Viatcheslav, Jurkschat Klaus
Format: Article
Language:English
Published: De Gruyter 2012-05-01
Series:Main Group Metal Chemistry
Subjects:
5-aza-2,8-dioxasilabicyclo[3.3.01.5]octanes
cyclic voltammetry
dft calculations
hypercoordinated silicon
x-ray diffraction analysis
Online Access:https://doi.org/10.1515/mgmc-2012-0005

Internet

https://doi.org/10.1515/mgmc-2012-0005

Similar Items