Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
A comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interfa...
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Format: | Article |
Language: | English |
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MDPI AG
2012-03-01
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Series: | Materials |
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Online Access: | http://www.mdpi.com/1996-1944/5/3/443/ |
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author | Masamichi Suzuki |
author_facet | Masamichi Suzuki |
author_sort | Masamichi Suzuki |
collection | DOAJ |
description | A comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interface with Si, which suppresses the formation of a low-permittivity Si oxide interfacial layer. Careful selection of the film deposition conditions has enabled successful deposition of an LaAlO3 gate dielectric film with an equivalent oxide thickness (EOT) of 0.31 nm. Direct contact with Si has been revealed to cause significant tensile strain to the Si in the interface region. The high stability of the effective work function with respect to the annealing conditions has been demonstrated through comparison with Hf-based dielectrics. It has also been shown that the effective work function can be tuned over a wide range by controlling the La/(La + Al) atomic ratio. In addition, gate-first n-MOSFETs with ultrathin EOT that use sulfur-implanted Schottky source/drain technology have been fabricated using a low-temperature process. |
first_indexed | 2024-04-12T13:07:46Z |
format | Article |
id | doaj.art-326ed7699a3a4e2d9e426b141d792c70 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-04-12T13:07:46Z |
publishDate | 2012-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Materials |
spelling | doaj.art-326ed7699a3a4e2d9e426b141d792c702022-12-22T03:31:58ZengMDPI AGMaterials1996-19442012-03-015344347710.3390/ma5030443Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS DevicesMasamichi SuzukiA comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interface with Si, which suppresses the formation of a low-permittivity Si oxide interfacial layer. Careful selection of the film deposition conditions has enabled successful deposition of an LaAlO3 gate dielectric film with an equivalent oxide thickness (EOT) of 0.31 nm. Direct contact with Si has been revealed to cause significant tensile strain to the Si in the interface region. The high stability of the effective work function with respect to the annealing conditions has been demonstrated through comparison with Hf-based dielectrics. It has also been shown that the effective work function can be tuned over a wide range by controlling the La/(La + Al) atomic ratio. In addition, gate-first n-MOSFETs with ultrathin EOT that use sulfur-implanted Schottky source/drain technology have been fabricated using a low-temperature process.http://www.mdpi.com/1996-1944/5/3/443/LaAlO3high-kgate dielectricsmetal gateMOSFETschottky source/drainEOTdirect contact |
spellingShingle | Masamichi Suzuki Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices Materials LaAlO3 high-k gate dielectrics metal gate MOSFET schottky source/drain EOT direct contact |
title | Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices |
title_full | Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices |
title_fullStr | Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices |
title_full_unstemmed | Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices |
title_short | Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices |
title_sort | comprehensive study of lanthanum aluminate high dielectric constant gate oxides for advanced cmos devices |
topic | LaAlO3 high-k gate dielectrics metal gate MOSFET schottky source/drain EOT direct contact |
url | http://www.mdpi.com/1996-1944/5/3/443/ |
work_keys_str_mv | AT masamichisuzuki comprehensivestudyoflanthanumaluminatehighdielectricconstantgateoxidesforadvancedcmosdevices |