Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices

A comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interfa...

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Main Author: Masamichi Suzuki
Format: Article
Language:English
Published: MDPI AG 2012-03-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/5/3/443/
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author Masamichi Suzuki
author_facet Masamichi Suzuki
author_sort Masamichi Suzuki
collection DOAJ
description A comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interface with Si, which suppresses the formation of a low-permittivity Si oxide interfacial layer. Careful selection of the film deposition conditions has enabled successful deposition of an LaAlO3 gate dielectric film with an equivalent oxide thickness (EOT) of 0.31 nm. Direct contact with Si has been revealed to cause significant tensile strain to the Si in the interface region. The high stability of the effective work function with respect to the annealing conditions has been demonstrated through comparison with Hf-based dielectrics. It has also been shown that the effective work function can be tuned over a wide range by controlling the La/(La + Al) atomic ratio. In addition, gate-first n-MOSFETs with ultrathin EOT that use sulfur-implanted Schottky source/drain technology have been fabricated using a low-temperature process.
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spelling doaj.art-326ed7699a3a4e2d9e426b141d792c702022-12-22T03:31:58ZengMDPI AGMaterials1996-19442012-03-015344347710.3390/ma5030443Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS DevicesMasamichi SuzukiA comprehensive study of the electrical and physical characteristics of Lanthanum Aluminate (LaAlO3) high-dielectric-constant gate oxides for advanced CMOS devices was performed. The most distinctive feature of LaAlO3 as compared with Hf-based high-k materials is the thermal stability at the interface with Si, which suppresses the formation of a low-permittivity Si oxide interfacial layer. Careful selection of the film deposition conditions has enabled successful deposition of an LaAlO3 gate dielectric film with an equivalent oxide thickness (EOT) of 0.31 nm. Direct contact with Si has been revealed to cause significant tensile strain to the Si in the interface region. The high stability of the effective work function with respect to the annealing conditions has been demonstrated through comparison with Hf-based dielectrics. It has also been shown that the effective work function can be tuned over a wide range by controlling the La/(La + Al) atomic ratio. In addition, gate-first n-MOSFETs with ultrathin EOT that use sulfur-implanted Schottky source/drain technology have been fabricated using a low-temperature process.http://www.mdpi.com/1996-1944/5/3/443/LaAlO3high-kgate dielectricsmetal gateMOSFETschottky source/drainEOTdirect contact
spellingShingle Masamichi Suzuki
Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
Materials
LaAlO3
high-k
gate dielectrics
metal gate
MOSFET
schottky source/drain
EOT
direct contact
title Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
title_full Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
title_fullStr Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
title_full_unstemmed Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
title_short Comprehensive Study of Lanthanum Aluminate High-Dielectric-Constant Gate Oxides for Advanced CMOS Devices
title_sort comprehensive study of lanthanum aluminate high dielectric constant gate oxides for advanced cmos devices
topic LaAlO3
high-k
gate dielectrics
metal gate
MOSFET
schottky source/drain
EOT
direct contact
url http://www.mdpi.com/1996-1944/5/3/443/
work_keys_str_mv AT masamichisuzuki comprehensivestudyoflanthanumaluminatehighdielectricconstantgateoxidesforadvancedcmosdevices